2 NVMe SSD's which slot to put OS on and does it matter?

which m2 slot to use
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2 form factor slot none of mentioned NVMe drives will work As it goes for throttling

″ SATA SSDs SATA SSDs DO NOT require an slot They connect to a hard drive using standard SATA data and power connections M Instead of connecting it via a SATA III cable, it plugs directly into the motherboard via the PCIe slot or into a traditional PCIe slot using an PCIe

slot เวปนอก 2 SSD slot will only work with 80 mm long 2280 SSDs And if you want proper compatibility, the size of your SSD and the slot should be the same  2 NVMe SSD If you are unsure whether your motherboard has this slot, check their specification or use CPU-Z to find out What to avoid when